Recent Advances on Conductive 2D Covalent Organic Frameworks.

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论文题目:Recent Advances on Conductive 2D Covalent Organic Frameworks.

论文作者:Gang Bian, Jun Yin, Jian Zhu*

发表期刊:Small, 17(22), 2006043, 2021    

Abstract: 

As a burgeoning family of crystalline porous copolymers, covalent  organic frameworks (COFs) allow precise atomic insertion of organic  components in the topology construction to form periodic networks and  ordered nanopores. Their 2D networks bear great similarities to graphene  analogs, and therefore are essential additions to the 2D family. Here,  the electronic properties of conductive 2D-COFs are reviewed and their  bonding strategies and structural characteristics are examined in  detail. The controlling approaches toward the morphologies of conductive  2D-COFs are further explored, followed by a discussion of their  applications in field-effect transistors, photodetectors, sensors,  catalysis, and energy storage. Finally, research challenges and  forthcoming developments are projected. The resulting survey reveals  that the extended porous 2D organic networks with conductive properties  will provide great opportunities and essential innovations in various  electronics and energy-related fields.