A Review on Metal–Organic Framework-Derived Porous Carbon-Based Novel Microwave Absorption Materials

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论文题目:A Review on Metal–Organic Framework-Derived Porous Carbon-Based Novel Microwave Absorption Materials

论文作者:Zhiwei Zhang, Zhihao Cai, Ziyuan Wang, Yaling Peng, Lun Xia, Suping Ma, Zhanzhao Yin, Yi Huang*

发表期刊:Nano-Micro Letters, 13(1), 56, 2021

Abstract: 

The development of microwave absorption materials (MAMs) is a  considerable important topic because our living space is crowed with  electromagnetic wave which threatens human's health. And MAMs are also  used in radar stealth for protecting the weapons from being detected.  Many nanomaterials were studied as MAMs, but not all of them have the  satisfactory performance. Recently, metal-organic frameworks (MOFs) have  attracted tremendous attention owing to their tunable chemical  structures, diverse properties, large specific surface area and uniform  pore distribution. MOF can transform to porous carbon (PC) which is  decorated with metal species at appropriate pyrolysis temperature.  However, the loss mechanism of pure MOF-derived PC is often relatively  simple. In order to further improve the MA performance, the MOFs coupled  with other loss materials are a widely studied method. In this review,  we summarize the theories of MA, the progress of different MOF-derived  PC-based MAMs, tunable chemical structures incorporated with dielectric  loss or magnetic loss materials. The different MA performance and  mechanisms are discussed in detail. Finally, the shortcomings,  challenges and perspectives of MOF-derived PC-based MAMs are also  presented. We hope this review could provide a new insight to design and  fabricate MOF-derived PC-based MAMs with better fundamental  understanding and practical application.