Recent Progress of Nanoscale Metal-Organic Frameworks in Synthesis and Battery Applications

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论文题目:Recent Progress of Nanoscale Metal-Organic Frameworks in Synthesis and Battery Applications

论文作者:Ming Zhong, Lingjun Kong, Kun Zhao, Yinghui Zhang, Na Li*, Xianhe Bu

发表期刊:Advanced Science, 8(4), 2001980, 2021    

Abstract: 

As one type of promising inorganic-organic hybrid crystal material,  metal-organic frameworks (MOFs) have attracted widespread attention in  many potential fields, particularly in energy storage and conversion.  Recently, effective strategies have been developed to construct uniform  nanoscale MOFs (NMOFs), which not only retain inherent advantages of  MOFs but also develop some improved superiorities, including shorter  diffusion pathway for guest transportation and more accessible active  sites for surface adsorption and reaction. Additonally, their nanometer  size provides more opportunity for post-functionalization and  hybridization. In this review, recent progress on the preparation of  NMOFs is summarized, primarily through bottom-up strategies including  reaction parameter- and coordination-assisted synthesis, and top-down  strategies such as liquid exfoliation and salt-template confinement.  Additionally, recent applications of NMOFs in batteries as electrodes,  separators, and electrolytes is discussed. Finally, some important  issues concerning the fabrication and application are emphasized, which  should be paid attention in future.